Nope, wiring is fine, as long as you maintain the wiring being "broken" and not pigtailed through.
The 120V smokes with ancilliary relays gets into a very grey point within code and what is and is not acceptable and what really should or should not be connected to a FACP. There's all sorts of ways to creatively interpret to what is permissible within code, however as an assembly, it's not compliant across the board in comparison to a 100% LV install.
Usually detectors like this are used to connect to monitoring points on commercial FACP's for the purpose of annunciation, not a fire alarm evacuation or signalling. Think hotel suite, dorm settings, etc.....you want to annunciate that an alarm may be occuring in a space, but based on false alarm criteria, dumping an entire building without an alarm being verified, not kosher. They're also used for remote annunciation, ie: hearing impaired or to trigger another system (dampers, doors, etc.)
There's plenty that will wave the flag of "I can do X or Y, the hardware supports it" at face value, however there are other factors to consider. In this case ,with 3 smokes and existing wiring, the cost is going to be the same and pretty much just as easy to do it with LV, barring removing the 120VAC from the smoke feeds and landing/capping it off in a suitable junction box separate from the LV.