Depending on the zone valve mechanics, not all of them would be considered Normally Closed. The White Rogers valves I have used have a stepper motor inside that rotates the valve body. The "Thermostat" input line would need to be kept closed, but the valve is drawing very little power to stay open. Opposed to a magnetic solenoid type valve where the coil would need to stay energized to keep the valve open.
Back to suitable for drinking water. Many of the valves are just a brass body with a steel valve that turns inside. Only 1 o-ring is used, which would probably be fine for the application. The o-ring isn't even in the direct flow of water. If I get a chance today I'll try find out if there is actually a drinking water spec on these valves.